The crystal structures of bis(2-aminoethyl 2-pyridyl sulfide)-copper(II) perchlorate and bis(2-aminoethyl 2-pyridyl sulfoxide)-copper(II) perchlorate.
نویسندگان
چکیده
منابع مشابه
2-(2-Pyridyl)pyridinium perchlorate, redetermined at 120 K: complex hydrogen-bonded sheets.
In the title compound, C10H9N2+.ClO4-, the ions are linked into complex sheets by the combination of one N-H...O and four independent C-H...O hydrogen bonds.
متن کاملBis(4-amino-3,5-di-2-pyridyl-4H-1,2,4-triazole)diaquanickel(II) bis(perchlorate)
In the mol-ecular structure of the centrosymmetric mononuclear complex [Ni(2-bpt)(2)(H(2)O)(2)](ClO(4))(2) [2-bpt = 4-amino-3,5-di-2-pyridyl-1,2,4-triazole, (C(12)H(10)N(6))], the central Ni(II) atom is six-coordinated by a pair of chelating 2-bpt ligands and two water mol-ecules. Inter-molecular O-H⋯N inter-actions link the monomeric units into a two-dimensional hydrogen-bonded (4,4) network, ...
متن کاملcatena-Poly[[[[2-(2-pyridyl-κN)-1H-benzimidazole-κN 3]copper(II)]-μ-l-methioninato-κ3 N,O:O′] perchlorate]
The structure of the title compound, {[Cu(C(5)H(10)NO(2)S)(C(12)H(9)N(3))]ClO(4)}(n), has ortho-rhom-bic symmetry. The chain structure is constructed from square-pyramidally coordinated Cu(II) atoms linked through l-methio-nate ligands. The chains propagate along the a-axis direction and are linked to perchlorate anions via N-H⋯O hydrogen bonds.
متن کاملDichlorido(di-2-pyridyl sulfide-κ2 N,N′)zinc(II)
The crystal structure of the title compound, [ZnCl(2)(C(10)H(8)N(2)S)], consists of a six-membered chelate ring in which the Zn atom is approximately tetra-hedrally coordinated by two chloride ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the ...
متن کامل(Di-2-pyridyl sulfide-κ2 N,N′)diiodidozinc(II)
The title compound, [ZnI(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring adopting a boat conformation in which the Zn atom is coordinated by two iodide ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand within a slightly distorted tetra-hedron. The Zn, S and I atoms are located on a crystallographic mirror plane. As usual for this type of complex, the sulfide ...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1986
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1986.1517